全文获取类型
收费全文 | 150004篇 |
免费 | 15228篇 |
国内免费 | 8557篇 |
专业分类
电工技术 | 10697篇 |
技术理论 | 29篇 |
综合类 | 14519篇 |
化学工业 | 22193篇 |
金属工艺 | 6523篇 |
机械仪表 | 10259篇 |
建筑科学 | 17252篇 |
矿业工程 | 6874篇 |
能源动力 | 7602篇 |
轻工业 | 9408篇 |
水利工程 | 4175篇 |
石油天然气 | 5997篇 |
武器工业 | 3193篇 |
无线电 | 13897篇 |
一般工业技术 | 12436篇 |
冶金工业 | 5824篇 |
原子能技术 | 1265篇 |
自动化技术 | 21646篇 |
出版年
2024年 | 267篇 |
2023年 | 1947篇 |
2022年 | 3722篇 |
2021年 | 4561篇 |
2020年 | 4702篇 |
2019年 | 3461篇 |
2018年 | 3262篇 |
2017年 | 4288篇 |
2016年 | 5010篇 |
2015年 | 5363篇 |
2014年 | 10514篇 |
2013年 | 8996篇 |
2012年 | 11359篇 |
2011年 | 11920篇 |
2010年 | 9160篇 |
2009年 | 9320篇 |
2008年 | 8767篇 |
2007年 | 10550篇 |
2006年 | 9461篇 |
2005年 | 8272篇 |
2004年 | 6880篇 |
2003年 | 6201篇 |
2002年 | 5038篇 |
2001年 | 4230篇 |
2000年 | 3375篇 |
1999年 | 2606篇 |
1998年 | 1984篇 |
1997年 | 1590篇 |
1996年 | 1331篇 |
1995年 | 1200篇 |
1994年 | 922篇 |
1993年 | 714篇 |
1992年 | 601篇 |
1991年 | 439篇 |
1990年 | 388篇 |
1989年 | 338篇 |
1988年 | 232篇 |
1987年 | 145篇 |
1986年 | 123篇 |
1985年 | 93篇 |
1984年 | 115篇 |
1983年 | 71篇 |
1982年 | 53篇 |
1981年 | 32篇 |
1980年 | 40篇 |
1979年 | 25篇 |
1978年 | 10篇 |
1966年 | 7篇 |
1959年 | 21篇 |
1951年 | 32篇 |
排序方式: 共有10000条查询结果,搜索用时 156 毫秒
61.
以方竹笋中提取的膳食纤维为研究对象,采用动态高压微射流(dynamic high-pressure micro-fluidization, DHPM)在不同压力条件(0,50,100,150,200 MPa)下进行处理,探究其对竹笋膳食纤维(bamboo shoots dietary fiber, BSDF)理化和结构特性的影响。结果表明,随着处理压力的增大,BSDF粒径先增大后减小,当处理压力为150 MPa时,粒径最小,为(370±11) nm,此条件下BSDF的持水力、持油力和膨胀力达到最大,较对照组分别提高了47.74%,50.54%,61.27%,且差异显著(P<0.05)。红外光谱分析表明DHPM处理不会改变BSDF的官能团,但会使BSDF内部的部分氢键断裂和半纤维素、木质素等发生降解;X射线衍射和热重分析表明DHPM处理不会引起BSDF的晶体结构改变,但晶体有序度会下降,进而导致其热稳定性降低;微观结构分析显示DHPM处理会使BSDF颗粒尺寸减小、表面粗糙、组织松散,且当处理压力为200 MPa时,颗粒发生团聚。综上,DHPM可以有效改善BSDF的理化性质,在膳食纤维改性方面具有一定的应用价值。 相似文献
62.
Through a combined computational fluid dynamics and discrete element method approach, the effect of the operating parameters on the hydrodynamics and heat‐transfer properties of gas‐solid two‐phase flows in a spouted bed are extensively investigated. Considering the high velocity in the fountain region, gas turbulence is resolved by employing the large‐eddy simulation. The rolling friction model is adopted for more precise predictions of solid behavior near the wall. Subsequently, the gas‐solid flow patterns, gas‐solid velocities, and temperature evolution are investigated. Moreover, different operating conditions and geometry configurations are evaluated with respect to heat‐transfer performance. The results provide a fundamental understanding of heat‐transfer mechanisms in spouted beds. 相似文献
63.
Vaidhegi Kugarajah Moogambigai Sugumar Elamathi Swaminathan Nagaraj Balasubramani Sangeetha Dharmalingam 《International Journal of Hydrogen Energy》2021,46(42):22134-22148
Hydrothermally prepared zinc oxide nanorods are sulphonated (S–ZnO NR) and incorporated into 15% Sulphonated Poly (1,4-Phenylene Ether Ether Sulfone) (SPEES) to improve the hydrophilicity, water uptake and ion transfer capacity. Water uptake and ion transfer capacity increased to 34.6 ± 0.6% and 2.0 ± 0.05 meq g?1 from 29.8 ± 0.3% and 1.4 ± 0.04 meq g?1 by adding 7.5 wt% S–ZnO NR to SPEES. Morphological studies show the prepared S–ZnO NR is well dispersed in the polymer matrix. SPEES +7.5 wt% S–ZnO NR membrane exhibits optimum performance after three-weeks of continual operation in a fabricated microbial fuel cell (MFC) to produce a maximum power density of 142 ± 1.2 mW m?2 with a reduced biofilm compared to plain SPEES (59 ± 0.8 mW m?2), unsulphonated filler incorporated SPEES (SPEES + 7.5 wt% ZnO, 68 ± 1.1 mW m?2) and Nafion (130 ± 1.5 mW m?2) thereby suggesting its suitability as a sustainable and improved cation exchange membrane (CEM) for MFCs. 相似文献
64.
Miroslav Kárný Marko Ruman 《International Journal of Adaptive Control and Signal Processing》2021,35(5):660-675
Any knowledge extraction relies (possibly implicitly) on a hypothesis about the modelled-data dependence. The extracted knowledge ultimately serves to a decision-making (DM). DM always faces uncertainty and this makes probabilistic modelling adequate. The inspected black-box modeling deals with “universal” approximators of the relevant probabilistic model. Finite mixtures with components in the exponential family are often exploited. Their attractiveness stems from their flexibility, the cluster interpretability of components and the existence of algorithms for processing high-dimensional data streams. They are even used in dynamic cases with mutually dependent data records while regression and auto-regression mixture components serve to the dependence modeling. These dynamic models, however, mostly assume data-independent component weights, that is, memoryless transitions between dynamic mixture components. Such mixtures are not universal approximators of dynamic probabilistic models. Formally, this follows from the fact that the set of finite probabilistic mixtures is not closed with respect to the conditioning, which is the key estimation and predictive operation. The paper overcomes this drawback by using ratios of finite mixtures as universally approximating dynamic parametric models. The paper motivates them, elaborates their approximate Bayesian recursive estimation and reveals their application potential. 相似文献
65.
Shanke Liu Hui Jin Yan Yang Lijun Yu 《International Journal of Hydrogen Energy》2021,46(54):27473-27482
Benzothiophene (BT) is a key sulfur-containing intermediate product in the thermal conversion process of coal and heavy oil. The migration process of the sulfur element may affect the thermal utilization design of BT. In this paper, BT was used as a model compound to simulate the supercritical water gasification (SCWG) process by molecular dynamics with a reactive force field (ReaxFF) method, and the laws of hydrogen production and sulfur migration mechanisms were obtained. Increasing the molecule number of supercritical water (SCW) and increasing the reaction temperature can enhance the generation of hydrogen and promote the conversion of organic sulfur to inorganic sulfur. Water was the main source of H2, and H2S was the main gaseous sulfur-containing product. SCW had a certain degree of oxidation due to a large number of hydroxyl radicals, which could increase the valence of sulfur. The conversion process of BT in SCW was mainly divided into four stages, including thiophene ring-opening; sulfur separation or carbon chain broke with sulfur retention; carbon chain cleaved, and gas generation. The lumped kinetic parameters of the conversion of sulfur in BT to inorganic sulfur were calculated, and the activation energy was 369.98 kJ/mol, which was much lower than those under pyrolysis conditions. This article aims to clarify the synergistic characteristics of hydrogen production and sulfur migration in the SCWG process of BT from the molecular perspective, which is expected to provide a theoretical basis for pollutant directional removal during hydrogen production by sulfur-containing organic matters in SCW. 相似文献
66.
67.
《International Journal of Hydrogen Energy》2021,46(62):31623-31633
In this paper, Pt nanoparticles (Pt NPs) deposited hybrid carbon support is prepared by modifying double-layered hollow carbon spheres(DLHCs)with poly(3,4-ethylenedioxythiophene) (PEDOT) and used as anode catalyst of methanol oxidation. The structure of nanocomposites is characterized by SEM, TEM, FT-IR, XRD and XPS, confirming the greatly enhanced synergistic effect between the PEDOT and DLHCs, and illustrating the uniform distribution of Pt NPs on the PEDOT/DLHCs composite surface with a small particle size (~2.63 nm). Cyclic voltammetry, chronoamperometry and impedance spectroscopy applied to determine the electrocatalytic activity of catalysts, it is found that the synthesized PEDOT/DLHCs/Pt possesses excellent characteristics such as large electrochemically active surface area and high mass activity of 59.45 m2 g−1 and 807 mA mg−1 in 0.5 M H2SO4 containing 1 M methanol solution, which is almost 1.24 and 2.8 times greater than those of commercial Pt/C, and the catalyst exhibits superior stability after 500 durability cycles. The enhanced electrocatalytic behavior can be ascribed to the excellent electronic conductivity of PEDOT-modified DLHCs and the strong binding of PEDOT/DLHCs to Pt NPs, suggesting that the PEDOT/DLHCs/Pt is a promising electrocatalyst for direct methanol fuel cell. 相似文献
68.
Xi Chen Zhengkun Yu Chen Yang Yao Chen Chao Jin Yuejiao Ding Wenbin Li Zhongmin Wan 《International Journal of Hydrogen Energy》2021,46(19):11127-11139
Flow field structure can largely determine the output performance of Polymer electrolyte membrane fuel cell. Excellent channel configuration accelerates electrochemical reactions in the catalytic layer, effectively avoiding flooding on the cathode side. In present study, a three-dimensional, multi-phase model of PEMFC with a 3D wave flow channel is established. CFD method is applied to optimize the geometry constructions of three-dimensional wave flow channels. The results reveal that 3D wave flow channel is overall better than straight channel in promoting reactant gases transport, removing liquid water accumulated in microporous layer and avoiding thermal stress concentration in the membrane. Moreover, results show the optimal flow channel minimum depth and wave length of the 3D wave flow channel are 0.45 mm and 2 mm, respectively. Due to the periodic geometric characteristics of the wave channel, the convective mass transfer is introduced, improving gas flow rate in through-plane direction. Furthermore, when the cell output voltage is 0.4 V, the current density in the novel channel is 23.8% higher than that of conventional channel. 相似文献
69.
Do T. Hue Rebel Skirving Tong Chen John L. Williams Cynthia D.K. Bottema Kiro Petrovski 《Journal of dairy science》2021,104(7):8164-8176
Colostrum is essential for good neonate health; however, it is not known whether different calves absorb the nutrients from colostrum equally well. In this study, the absorption of protein, IgG, and γ-glutamyl transferase was compared in newborn dairy bull calves for 1 wk after feeding colostrum from different sources. Thirty-five Holstein-Friesian bull calves were randomly allocated into 3 groups and fed colostrum within 4 h after birth. Group A calves (n = 12) were bottle fed colostrum from their own dam for 3 d. Colostrum from these group A cows was also used as foster cow colostrum for the group B calves (n = 12), such that each group A and B calf pair received identical colostrum from each milking of the respective group A dam (10% of birth weight per day). The group C calves (n = 11) were fed 1 bottle (2 L) of pooled colostrum and transition milk (referred to as pooled colostrum), as was the standard practice on the dairy farm. The pooled colostrum was collected from the other dairy cows on the farm 0 to 4 d postpartum and stored at 4°C for less than 12 h. Blood was sampled from calves before the first feeding and at 1, 2, 3, and 7 d after birth. Levels of total solids, total protein, and IgG were higher in the dam colostrum than in the pooled colostrum. At birth, there were no differences between the calf groups for any measurements, and all calves had very low IgG levels. After receiving colostrum, the glucose, plasma γ-glutamyl transferase, serum total protein, and IgG concentrations increased significantly in all calves. There were no differences in any blood measurements at any time point between the pairs of group A and group B calves that received colostrum from the same cow except for the IgG concentration 2 d after birth. However, the group A calves had a higher total serum protein level and IgG concentration than the group C calves for all the time points after the first feeding. The group B calves had a higher IgG concentration than the group C calves on d 1, 2, and 7 after birth. Compared with groups A and B, there was no difference in the proportion of calves in group C that failed to have passive immunity transferred adequately based on the IgG threshold (<10 g/L). Thus, the calves receiving identical colostrum from the same cow had the same levels of IgG, and even the pooled colostrum provided sufficient transfer of IgG as the calves were fed within 4 h after birth. 相似文献
70.
《Ceramics International》2022,48(17):24953-24964